Influence of the soliton in anharmonic molecular crystals with temperature on Mössbauer effect

The influence of a soliton on the properties of the M?ssbauer effect resulting from the gamma-active nuclei situated at lattice sites in quasi-one-dimensional anharmonically organic molecular chains, in which the active nuclei emit gamma-photons, has been theoretically studied by a quantum vibrational model. An expression for the gamma-radiated M?ssbauer transition probability as a function of the temperature and non-linear interaction has been obtained. Finally we give some new properties of this effect from numerical calculation in such a case, which present a way to experimentally confirm the soliton existence in molecular crystals. Received 9 April 1998 and Received in final form 11 December 1998     

The domain of partial attraction of a Poisson law

Groshev gave a characterization of the union of domains of partial attraction of all Poisson laws in 1941. His classical condition is expressed by the underlying distribution function and disguises the role of the mean of the attracting distribution. In the present paper we start out from results of the recent probabilistic approach and derive characterizations for any fixed >0 in terms of the underlying quantile function. The approach identifies the portion of the sample that contributes the limiting Poisson behavior of the sum, delineates the effect of extreme values, and leads to necessary and sufficient conditions all involving . It turns out that the limiting Poisson distributions arise in two qualitatively different ways depending upon whether >1 or <1. A concrete construction, illustrating all the results, also shows that in the boundary case when =1 both possibilities may occur.     

Evaluation of dissociation constants of ammonium ion in aqueous lithium perchlorate and lithium chloride-sodium chloride mixed solutions

The Pitzer approach has been applied to the evaluation of dissociation constants of ammonium ion in lithium perchlorate and lithium chloride-sodium chloride mixed solutions at 25°C. The calculated values showed good agreement with the observed values, provided all the higher-order interaction terms ('s and 's) concerned were introduced. The unknown (NH₄LiClO₄) value was determined from the isopiestic measurements of NH₄ClO₄–LiClO₄ mixed solutions. Parameters in the Pitzer formalism for ammonia-ion interactions involved in LiCl and NaCl media were determined by use of the activity coefficients of ammonia measured in LiCl–NaCl mixed solutions by a transpiration method.     

一类有条件异方差的非线性自回归模型的高阶矩

本文对一类非线性时间序列模型ｘｔ＝φ（ｘｔ－１，…，ｘｔ－ｐ）＋εｔｈ（ｘｔ－１，…，ｘｔ－ｐ）给出了高阶矩的存在条件。     

Higher order dispersive effects in regularized Boussinesq equation

In this paper, we consider the higher order Boussinesq (HBq) equation which models the bi-directional propagation of longitudinal waves in various continuous media. The equation contains the higher order effects of frequency dispersion. The present study is devoted to the numerical investigation of the HBq equation. For this aim a numerical scheme combining the Fourier pseudo-spectral method in space and a Runge–Kutta method in time is constructed. The convergence of semi-discrete scheme is proved in an appropriate Sobolev space. To investigate the higher order dispersive effects and nonlinear effects on the solutions of HBq equation, propagation of single solitary wave, head-on collision of solitary waves and blow-up solutions are considered.     

Analysis of chaos behaviors of a bistable piezoelectric cantilever power generation system by the second-order Melnikov function

By applying the second order Melnikov function, the chaos behaviors of a bistable piezoelectric cantilever power generation system are analyzed. Firstly, the conditions for emerging chaos of the system are derived by the second order Melnikov function. Secondly, the effects of each item in chaos threshold expression are analyzed. The excitation frequency and resistance values, which have the most influ-ence on chaos threshold value, are found. The result from the second order Melnikov function is more accurate compared with that from the first order Melnikov function. Finally, the attraction basins of large amplitude motions under different exciting frequency, exciting amplitude, and resistance para-meters are given.     

复合材料特征值的高阶多尺度Rayleigh商校正

本文讨论了周期结构复合材料特征值的多尺度计算,提出了高阶多尺度Rayleigh商校正算法,并给出了收敛性分析. 最后,通过大量数值实验结果表明,新算法是有效且必要的.     

奇异摄动问题内罚间断有限方法的最优阶一致收敛性分析

本文在Bakhvalov-Shishkin网格上分析了采用高次元的内罚间断有限元方法求解一维对流扩散型奇异摄动问题的最优阶一致收敛性. 取k(k≥1)次分片多项式和网格剖分单元数为N时,在能量范数度量下, Bakhvalov-Shishkin网格上可获得O(N^-k)的一致误差估计. 在数值算例部分对理论分析结果进行了验证.     

Construction of a CPA contraction metric for periodic orbits using semidefinite optimization

A Riemannian metric with a local contraction property can be used to prove existence and uniqueness of a periodic orbit and determine a subset of its basin of attraction. While the existence of such a contraction metric is equivalent to the existence of an exponentially stable periodic orbit, the explicit construction of the metric is a difficult problem.In this paper, the construction of such a contraction metric is achieved by formulating it as an equivalent problem, namely a feasibility problem in semidefinite optimization. The contraction metric, a matrix-valued function, is constructed as a continuous piecewise affine (CPA) function, which is affine on each simplex of a triangulation of the phase space. The contraction conditions are formulated as conditions on the values at the vertices.The paper states a semidefinite optimization problem. We prove on the one hand that a feasible solution of the optimization problem determines a CPA contraction metric and on the other hand that the optimization problem is always feasible if the system has an exponentially stable periodic orbit and the triangulation is fine enough. An objective function can be used to obtain a bound on the largest Floquet exponent of the periodic orbit.